A unique stepped multifunctionality of perfluorinated aryl compound and its versatile use in synthesizing grafted polymers with controlled structures and topologies

Z Zhao, X Ma, A Zhang, N Song

Index: Zhao, Zhenhua; Ma, Xiaohua; Zhang, Aixin; Song, Naiheng Journal of Polymer Science, Part A: Polymer Chemistry, 2011 , vol. 49, # 11 p. 2423 - 2433

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Citation Number: 4

Abstract

Abstract A unique stepped multifunctionality of perfluorinated aryl compound for the first time was studied by using model reactions between 2, 5-dipentafluorophenyl-1, 3, 4-oxadiazole (FPOx) and mono functional p-cresol at different reaction conditions. Four distinctively different levels of reactivity were discovered for the para and ortho C [BOND] F of FPOx, which could be easily triggered by the reaction temperature in the range of rt to 160 C. C [ ...