Preparation, characterization, and reactions of 16-electron Ta (η 5-C 5 Me 5)(η 3-1-phenylallyl) 2

…, Y Yamanaka, Y Gohro, A Nakamura

Index: Mashima, Kazushi; Yamanaka, Yoshimichi; Gohro, Yoshihiko; Nakamura, Akira Journal of Organometallic Chemistry, 1993 , vol. 459, # 1-2 p. 131 - 138

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Citation Number: 7

Abstract

Abstract Treatment of CpTaCl 4 with 4 equiv of phenylallylMgBr in THF afforded CpTa (l- phenylallyl) 2 (2), whose structure was characterized by a single crystal X-ray study as 16- electron two legged piano stool with two allyl moieties in supine-supine geometry. In this ...