1, 10??Phenanthroline??Catalyzed Tandem Reaction of 2??Iodoanilines with Isothiocyanates in Water

W Zhang, Y Yue, D Yu, L Song, YY Xu…

Index: Zhang, Wu; Yue, Yun; Yu, Dan; Song, Lei; Xu, Yang-Yang; Tian, Yu-Jie; Guo, Yu-Jun Advanced Synthesis and Catalysis, 2012 , vol. 354, # 11-12 p. 2283 - 2287

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Citation Number: 13

Abstract

Abstract The 1, 10-phenanthroline-catalyzed tandem reaction of 2-iodoaniline with isothiocyanate in water is described, which provides an environmentally benign, efficient and simple route for the preparation of 2-aminobenzothiazoles. The present tandem process shows broad substrate scope in the absence of transition metals and phase-transfer catalysts.