Reactions of some aromatic nitro compounds with alkali metal amides

SS Gandhi, MS Gibson, ML Kaldas…

Index: Gandhi,S.S. et al. Journal of Organic Chemistry, 1979 , vol. 44, # 25 p. 4705 - 4707

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Citation Number: 6

Abstract

4-Nitrobenzophenone would be expected to undergo reversible addition of amide ion at the carbonyl group and eventually to yield benzoic acid and nitrobenzene if cleavage followed. 2 Benzoic acid was in fact isolated from a somewhat sluggish reaction of 4- nitrobenzophenone and potassamide nn ammonia from which 45% of the ketone was recovered, but no nitrobenzene was detected. This became understandable when it was ...