Disparate Behavior of Carbonyl and Thiocarbonyl Compounds: Acyl Chlorides vs Thiocarbonyl Chlorides and Isocyanates vs Isothiocyanates

KB Wiberg, Y Wang, SJ Miller…

Index: Staudinger; Siegwart Helvetica Chimica Acta, 1920 , vol. 3, p. 838

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Citation Number: 11

Abstract

... Volume: Page: ... with methanol that indicate the former to be 12 times more reactive than the latter at 0 °C.(4, 5) In order to have a direct comparison at 25 °C, thiobenzoyl chloride was prepared following the procedure of Staudinger and Siegwart(9) and ...