Formation of (η-Cyclopentadienyl)(1, 2-ethylenedithiolato, 1, 2-ethylenediselenolato, and 2-selenolatoethylenethiolato-S, Se) cobalt (III) Complexes in a One-Pot- …

…, K Dohki, N Kobayashi, T Akiyama, A Sugimori

Index: Kajitani; Ochiai; Dohki; Kobayashi; Akiyama; Sugimori Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 10 p. 3266 - 3271

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Citation Number: 18

Abstract

A one-pot-reaction of (η-cyclopentadienyl)(1, 5-cyclooctadiene or dicarbonyl) cobalt (I) with alkyne (diphenylacetylene and phenylacetylene) and a mixture of S 8 and Se 8 gives (η- cyclopentadienyl)(2-selenolatoethylenethiolato-S, Se) cobalt (III) complex in addition to the corresponding dithiolato and diselenolato complexes. When phenylacetylene was used as an alkyne, a (2-phenyl-2-selenolatoethylenethiolato-S, Se) cobalt (III) complex was formed ...