. alpha.-Anions. VII. Direct oxidation of enolate anions to 2-hydroperoxy-and 2-hydroxycarboxylic acids and esters

DA Konen, LS Silbert, PE Pfeffer

Index: Konen,D.A. et al. Journal of Organic Chemistry, 1975 , vol. 40, p. 3253 - 3258

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Citation Number: 69

Abstract

Direct Oxidation of Enolate Anions J. Org. Chem., Vol. 40, No. 22, 1975 3253 analyses before and after double bond hydrogenation, comparisons with reference compounds [methyl 9 (10)-and 12-hydroxy-9-octadecenoate, 12-hydroxyoctadecanoate, and 9, lO-and 10, 12-dihydroxyoctadecanoate] and reported fragmentation scheme~.~~ J~*~~ The 9, lO- dihydroxy (threo) compound is derived from methyl oleate; the 10, 12-dihydroxy (threo) ...