e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
The X-ray crystal structure, conformation and preparation of anti-3, 3, 6, 6-tetramethylthiepane-4, 5-diol: stereochemistry of reduction of a heterocyclic α-hydroxy …
N Feeder, MJ Ginnelly, RVH Jones…
Index: Feeder, Neil; Ginnelly, Michael J.; Jones, Ray V. H.; O'Sullivan, Susan; Warren, Stuart; Wyatt, Paul Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 22 p. 3479 - 3483
The X-ray crystal structure and conformation of the anti title diol is described together with stereoselective syntheses of syn-and anti-diols from a readily available acyloin. Some control of the stereoselective reduction of α-hydroxy ketones by chelating and non-chelating reducing agents is possible.
