Heteroatom Chemistry

TBAF Promoted Formation of Symmetrical Trisulfides

S Lach, D Witt

Index: Lach, Slawomir; Witt, Dariusz Heteroatom Chemistry, 2014 , vol. 25, # 1 p. 10 - 14

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Citation Number: 4

Abstract

ABSTRACT We have developed a new method for the synthesis of functionalized symmetrical trisulfides based on (5, 5-dimethyl-2-thioxo-1, 3, 2-dioxa-phosphorin-2-yl) disulfanyl derivatives prepared from readily available 5, 5-dimethyl-2-sul-fanyl-2-thioxo-1, 3, 2-dioxaphosphorinane or bis (5, 5-dimethyl-2-thioxo-1, 3, 2-dioxaphosphorinan-2-yl) disulfide. The symmetrical trisulfides can be obtained from aliphatic and aromatic thiols ...