Aliphatic semidiones. XXV. Bicyclo [n. 2.1] alkane-2, 3-semidiones

GA Russell, GW Holland, KY Chang…

Index: Russell,G.A. et al. Journal of the American Chemical Society, 1974 , vol. 96, p. 7237 - 7248

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Citation Number: 24

Abstract

Abstract: The esr spectra of a number of bicyclo [2.2. l] heptane-2, 3-semidiones and bicyclo [3.2. l] octane-2, 3-semidiones are reported, including tri-and tetracyclic derivatives. Assignments of hyperfine splitting constants have been made by studies of deuterium and alkyl derivatives. A number of long range transoid, coplanar interactions between protons and the electron spin are reported, discussed, and analyzed in terms of valence bond ...