Journal of the American Chemical Society 2010-04-14

Cationic palladium(II) catalysis: C-H activation/Suzuki-Miyaura couplings at room temperature.

Takashi Nishikata, Alexander R Abela, Shenlin Huang, Bruce H Lipshutz

Index: J. Am. Chem. Soc. 132 , 4978, (2010)

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Abstract

Cationic palladium(II) catalyst realized facile C-H activation of aryl urea with arylboronic acids at room temperature. This reaction is extremely mild to carry out aromatic C-H activations through electrophilic substitution.