Anion sensing and F(-)-induced reversible photoreaction of D-π-A type dye containing imidazole moiety as donor.
Seon-Yeong Gwon, Sung-Hoon Kim
Index: Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 117 , 810-3, (2014)
Full Text: HTML
Abstract
A new donor-π-acceptor (D-π-A) type dye was synthesized by the condensation reaction between 2-cyanomethylene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran and 4-imidazolecarboxaldehyde. The chemical structure of the dye was characterized by (1)H NMR, EA and MS. A novel chromogenic dye based on imidazole as donor unit and furan as acceptor unit displayed marked UV-visible absorption changes in the presence of fluoride ion. The levels of energy potential and the electron density distributions of this dye were also simulated and discussed using computational model calculation. The reversible photoreaction of the dye-F(-) complex was studied by time-dependent UV-visible absorption spectra. Copyright © 2012 Elsevier B.V. All rights reserved.
Related Compounds
| Structure | Name/CAS No. | Molecular Formula | Articles |
|---|---|---|---|
 |
1H-Imidazole-4-carbaldehyde
CAS:3034-50-2 |
C4H4N2O |
|
Endosomal pH responsive polymers for efficient cancer target...
2014-07-01 [Colloids Surf. B Biointerfaces 119 , 55-65, (2014)] |
|
Convenient synthesis of alkyl esters of urocanic acid.
1981-01-01 [J. Pharm. Sci. 70(1) , 98-9, (1981)] |
|
[Org. Process Res. Dev. 11 , 206, (2007)] |
|
Chromene and Imidazole Based D-p-A Chemosensor Preparation a...
[Mol. Cryst. Liq. Cryst. 599(1) , 16-22., (2014)] |
|
Spontaneous Resolution Induced by a Chiral Ni (II) Complex w...
[Bull. Korean Chem. Soc. 36(3) , 838-842, (2015)] |