… )(CF 3) 2, and HOC (Ar)(CF 3) 2 (Ar= 4-C 6 H 4 (t-Bu), 2, 4, 6-C 6 H 2 (CF 3) 3, 4-Si (i-Pr) 3-2, 6-C 6 H 2 (CF 3) 2, 3, 5-C 6 H 3 (CH 3) 2), and 2-C 6 H 4 (C (OH)(CF 3) 2)

TJ Barbarich, BG Nolan, S Tsujioka, SM Miller…

Index: Barbarich; Nolan; Tsujioka; Miller; Anderson; Strauss Journal of Fluorine Chemistry, 2001 , vol. 112, # 2 p. 335 - 342

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Citation Number: 15

Abstract

Five new polyfluoroalcohols, HOC (cyclo-C6H11) 2 (CF3), HO (cyclo-C6H11)(CF3) 2, HOC (2, 4, 6-C6H2 (CF3) 3)(CF3) 2, HOC (4-Si (i-Pr) 3-2, 6-C6H2 (CF3) 2)(CF3) 2, and HOC (3, 5- C6H3 (CH3) 2)(CF3) 2, have been synthesized, and new procedures with improved yields for two known polyfluoroalcohols (HOC (cyclo-C6H11)(CF3) 2, HOC (4-C6H4 (t-Bu))(CF3) 2) have been developed. Variable temperature 19F NMR spectra and the X-ray structure of ...