Tetrahedron Letters

A new ring transformation: Synthesis of 5, 5-dimethyl-3-oxo-1-pyrroline 1-oxides from 6, 6-dimethyl-4-oxo-5, 6-dihydro-1, 2, 4h-oxazines

C Deshayes, S Gelin

Index: Deshayes, Christian; Gelin, Suzanne Tetrahedron Letters, 1981 , vol. 22, # 27 p. 2557 - 2560

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Citation Number: 9

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The nitrosation of some γ,δ-unsaturated β-diketo compounds affords the 3-substituted 4-oxo-5,6-dihydro-1,2,4H-oxazines. These compounds are converted to the isomeric 3-oxo-1-pyrroline 1-oxides by a facile thermal rearrangement. ... : 2.00 (s, CH 3 ); 2.20 (s, ...