e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Structural effects in solvolytic reactions. 17. Solvolysis of 1-aryl-1-cyclopropyl-1-ethyl p-nitrobenzoates. Major increases in electron supply by the cyclopropyl group …
HC Brown, EN Peters…
Index: Brown,H.C. et al. Journal of the American Chemical Society, 1977 , vol. 99, # 2 p. 505 - 509
Abstract: The rates of solvolysis in 80% acetone of I-aryl-1-cyclopropyl-I-ethyl p- nitrobenzoates containing representative substituents in the aryl ring (p-CH30, pH, p-CF3, 3, 5-(CF3) 2) were determined and compared with the rates for the 2-aryl-3-methyl-2-butyl p- nitrobenzoates. Substituted cyclopropyl derivatives (2', 2'-dimethylcyclopropyl and 2'. 2'- dichlorocyclopropyl) were also synthesized and the rates determined. The p+ value for the ...
