Tetrahedron Letters

6-dimethylamino-6-lithiofulvene, a novel 6-fulvenyl anion of potential synthetic utility

T Kawase, S Fujino, M Oda

Index: Kawase; Fujino; Oda Tetrahedron Letters, 1990 , vol. 31, # 4 p. 545 - 548

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Citation Number: 7

Abstract

Abstract Treatment of 6.6-bis (dimethylamino) fulvene with 2.2 equiv. of lithium napthalenide in THF generates, via two-electron reduction and deamination, 6-dimethylamino-6 lithiofulvene which is a new 6-fulvenyl anion of potential utility for the synthesis of a variety of