Developmental photochemistry. Norrish Type II reaction

DC Neckers, RM Kellogg, WL Prins…

Index: Neckers,D.C. et al. Journal of Organic Chemistry, 1971 , vol. 36, p. 1838 - 1840

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Citation Number: 12

Abstract

Irradiation Starting time, Temp, material Registry no. hr OC Product (yield,%) an= 6 6268-58- 2 24 40 Butadiene-l, 3 (50) n= 7 28861-21-4 20 40 Pentadiene-1, 4 (46) 60 40 Pentadiene-l, 4 (51) n= 8 6268-61-7 20 30 He&diene-1, 5 (63) n= 5 28861-22-5 20 30 Allene (0) ba Based on starting ketone. b l-Phenylpenta-4-en-2-one was the only isolated product. flask designed was sufficient so that solid ketone slowly went into solution as the photochemical reaction ...