Organic letters

Aldehyde-selective Wacker oxidation in a thiyl-mediated vinyl group transfer route to daunosamine

GK Friestad, T Jiang, AK Mathies

Index: Abbaci, Belgacem; Florent, Jean-Claude; Monneret, Claude Bulletin de la Societe Chimique de France, 1989 , # 5 p. 667 - 672

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Citation Number: 34

Abstract

... (c) Zhou, P.; Chen, B.; Davis, FA Tetrahedron 2004, 60, 8003−8030. ... Tin-mediated 5-exo radical cyclization of α-hydroxy hydrazones using a Si-tethered bromomethyl group, followed by oxidative removal of the tether, provides anti-2-hydrazino 1,3-diols in good yield. ...