The Journal of Organic Chemistry

The Acylation of Benzamidoximes

JA Durden Jr, DL Heywood

Index: Durden,J.A.; Heywood,D.L. Journal of Organic Chemistry, 1965 , vol. 30, p. 4359 - 4361

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Citation Number: 10

Abstract

The formation of the urea derivative is most likely the result of an initial 0 acylation followed by a Beckmanntype rearrangement. The analogous reaction has been reported for 0- sulfonylamidoximes. lo The present example is apparently the first one involving an acylamidoxime and is explicable because of the high migratory tendency of the 4- methoxyphenyl group coupled with the stability of the trichloroacetate anion. The results ...