Photosubstitution and photoreduction of pyrene and 1??halopyrenes

…, FJ Rietmeyer, J Cornelisse

Index: Tintel, C.; Rietmeyer, F. J.; Cornelisse, J. Recueil: Journal of the Royal Netherlands Chemical Society, 1983 , vol. 102, # 4 p. 224 - 228

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Citation Number: 8

Abstract

Abstract Upon irradiation, pyrene reacts with cyanide to give 1-cyanopyrene and with amide to give 1-aminopyrene. With oxygen nucleophiles no reaction takes place. Irradiation of pyrene in the presence of diethyl malonate anion yields 4, 5, 9, 10-tetrahydropyrene in high