Russian journal of organic chemistry

Substituted 5-Dinitromethyl-3-phenyl-1, 2, 4-oxadiazoles in Reactions with Arylethenes

AG Tyrkov

Index: Tyrkov Russian Journal of Organic Chemistry, 2003 , vol. 39, # 6 p. 890 - 892

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Citation Number: 3

Abstract

Abstract Reactions of substituted 5-dinitromethyl-3-phenyl-1'2'4-oxadiazoles with arylethenes of variousnucleophilicity, number, position of substituents attached to the double bond give rise to nitroalkenes andsecondary products resulting from α-nitroketones or nitroalcohols O-alkylation. The direction of transforma-tions in the arising ion pair is governed predominantly by steric effects.