Tetrahedron Letters

Cumulene photochemistry: phenyl and hydrogen migration in phenylallene photoreactions

MW Klett, RP Johnson

Index: Klett, Michael W.; Johnson, Richard P. Tetrahedron Letters, 1983 , vol. 24, # 25 p. 2523 - 2526

Full Text: HTML

Citation Number: 12

Abstract

... CUMULENE PHOTOCHEMISTRY: PHENYL AND HYDROGEN MIGRATION IN PHENYLALLENE PHOTOREACTIONS Michael W. Klett and Richard P. Johnson* Department of Chemistry Iowa State University Ames, Iowa 50011 a~A ,: Photoreactions of tetra- and triphenylallene and 1,3,3-triphenylcyclopropene in hydrocarbon solvents are reported. Intermediacy of vinylcarbenes is supported by independent generation experiments. ...