Abstract Under microwave irradiation, the one-pot multicomponent condensation reaction of three molar aromatic aldehydes with two molar cyclic ketones having free α, α′-methylene positions such as cyclopentanone or cyclohexanone in the presence of ammonium acetate and acetic acid afforded dicyclocalkenopyridines with two α-arylidene groups in good yields. In similar reaction conditions, 1-tetralone, which has only one α-methylene position, ...