The Journal of Organic Chemistry

Formation of thiocarbamates in the oxidative condensation of amines and organic N-chloroamines with potassium ethyl xanthate

FE Scully Jr, T Ortega

Index: Scully, Frank E.; Ortega, Teresita Journal of Organic Chemistry, 1989 , vol. 54, # 12 p. 2978 - 2980

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Citation Number: 11

Abstract

We have been investigating new reactions of organic N-chloroamines in an effort to develop methods of derivatizing them for analysis in dilute aqueous solution. In a series of papers Smith et al.'-" reported that the sulfur moiety of certain thiols, dithiocarbamates, and carbodithioates reacted with organic N-chloroamines or with amines in the presence of iodine to form sulfenamide produck Although he examined the reaction of xanthate salts ...