Structure and reactivity in Langmuir films of amphiphilic alkyl and thio-alkyl esters of α-amino acids at the air/water interface

R Eliash, I Weissbuch, MJ Weygand…

Index: Eliash, Ran; Weissbuch, Isabelle; Weygand, Markus J.; Kjaer, Kristian; Leiserowitz, Leslie; Lahav, Meir Journal of Physical Chemistry B, 2004 , vol. 108, # 22 p. 7228 - 7240

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Citation Number: 15

Abstract

The structure and reactivity of alkyl esters of several α-amino acids self-assembled at the air/water interface have been investigated as part of our studies on mechanisms that are possibly relevant for the generation of homochiral prebiotic peptides. Grazing incidence X- ray diffraction (GIXD) studies of monolayers of racemic and enantiopure alkyl esters and thio- esters of alanine on the water surface demonstrated that these racemates self-assemble ...