Palladium-catalyzed CC coupling under thermomorphic conditions

DE Bergbreiter, PL Osburn, A Wilson…

Index: Bergbreiter, David E.; Osburn, Philip L.; Wilson, Allan; Sink, Erin M. Journal of the American Chemical Society, 2000 , vol. 122, # 38 p. 9058 - 9064

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Citation Number: 303

Abstract

Liquid-liquid biphasic systems that exhibit an increase in phase miscibility at elevated temperature together with soluble polymer-bound catalysts that have a strong phase preference at ambient temperature are described. In such systems, product isolation and catalyst recovery are effected by a liquid/liquid separation. This report describes the use of such thermomorphic catalyst recovery systems for palladium-catalyzed carbon-carbon ...

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