Generation and reactivity of the acetylacetonyl radical

YL Chow, GE Buono-Core

Index: Chow, Yuan L.; Buono-Core, Gonzalo E. Journal of the American Chemical Society, 1982 , vol. 104, # 13 p. 3770 - 3771

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Citation Number: 11

Abstract

Cu (acac) z, involves the paramagnetic interaction of the triplet excited state of aryl ketones with the complex. It has been proposed that this occurs by a mixture of charge-transfer and spinexchange processes leading to the intermediacy of the acetylacetonyl This radical has also been implicated in the oxidation of acetyla~ etone~~ with metal ions; for example, manganese (II1) acetate in acetic acid. 3 As the generation of a prima facie acetylacetonyl ...