e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Electrochimica Acta

Electrochemical oxidation of organic compounds in fluorosulfuric acid—III. Voltammetric investigation of aromatic carboxylic acids and acylium ions

AP Rudenko, MJ Zarubin, NS Barsheva, F Pragst

Index: Rudenko; Salfetnikova; Vasil'ev Russian Journal of Organic Chemistry, 1996 , vol. 32, # 10 p. 1447 - 1470

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Citation Number: 4

Abstract

Abstract The anodic behavior of a series of substituted benzoic acids 1a–1w and of the corresponding benzoylium ions 5 is investigated by cyclic voltammetry in fluorosulfuric acid at− 76 C. The acids are oxidized to cation radicals, the stability of which decreases with

Pentamethylbenzoic acid Structure

Pentamethylbenz...

~63%

PENTAMETHYLBENZONITRILE Structure

PENTAMETHYLBENZ...

2,4-Dimethylbenzoic acid Structure

2,4-Dimethylben...

~53%

2,4-DIMETHYLBENZONITRILE Structure

2,4-DIMETHYLBEN...

2,4,6-Trimethylbenzoic acid Structure

2,4,6-Trimethyl...

~66%

Mesitonitrile Structure

Benzoic acid,2,3,5,6-tetramethyl- Structure

Benzoic acid,2,...

~65%

Benzonitrile,2,3,5,6-tetramethyl- Structure

Benzonitrile,2,...

2,3,4,5-tetramethylbenzoic acid Structure

2,3,4,5-tetrame...

~52%

2,3,4,5-tetramethylbenzonitrile Structure

2,3,4,5-tetrame...

4-tert-Butyl-2,6-dimethylbenzoic acid Structure

4-tert-Butyl-2,...

~49%

4-tert-butyl-2,6-dimethylbenzonitrile Structure

4-tert-butyl-2,...

3-Methylbenzoic acid Structure

3-Methylbenzoic acid

~56%

3-methylbenzonitrile Structure

3-methylbenzonitrile

2,4,5-Trimethylbenzoic Acid Structure

2,4,5-Trimethyl...

~62%

2 4 5-TRIMETHYLBENZONITRILE Structure

2 4 5-TRIMETHYL...

2,5-Dimethylbenzoic acid Structure

2,5-Dimethylben...

~46%

2,5-Dimethylbenzonitrile Structure

2,5-Dimethylben...

METHYL FLUOROSULFONATE Structure

METHYL FLUOROSU...

3,5-Dimethylbenzonitrile Structure

3,5-Dimethylben...

~15%

Benzamide, N,3,5-trimethyl- (9CI) Structure

Benzamide, N,3,...

3,5-Dimethylbenzoic acid Structure

3,5-Dimethylben...

~%

Benzamide, N,3,5-trimethyl- (9CI) Structure

Benzamide, N,3,...

α-isodurylic acid Structure

α-isodurylic acid

~33%

2,3,5-trimethylbenzonitrile Structure

2,3,5-trimethyl...

2,3,4,6-tetramethylbenzoic acid Structure

2,3,4,6-tetrame...

~55%

2,3,4,6-tetramethylbenzonitrile Structure

2,3,4,6-tetrame...

A facile synthetic route to some arylmalononitriles.

[Suzuki, Hitomi; Kobayashi, Tsutomu; Osuka, Atsuhiro Chemistry Letters, 1983 , p. 589 - 590]