Journal of Organic Chemistry 2005-10-28

Syntheses of S-enantiomers of hanishin, longamide B, and longamide B methyl ester from L-aspartic acid beta-methyl ester: establishment of absolute stereochemistry.

Jignesh Patel, Nadia Pelloux-Léon, Frédéric Minassian, Yannick Vallée

Index: J. Org. Chem. 70 , 9081-9084, (2005)

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Abstract

[reaction: see text] Total syntheses of enantiopure hanishin, longamide B, and longamide B methyl ester are described. Absolute configurations of these natural products have been established.