Organic Letters 2001-01-01

A catalyst for efficient and highly enantioselective hydrogenation of aromatic, heteroaromatic, and alpha,beta-unsaturated ketones

Burk, Hems, Herzberg, Malan, Zanotti-Gerosa

Index: Org. Lett. 2 , 4173, (2000)

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Abstract

PhanePhos-ruthenium-diamine complexes catalyze the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic, and alpha, beta-unsaturated ketones with high activity and excellent enantioselectivity.

Structure	Name/CAS No.	Molecular Formula	Articles
	Tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene-5,11-diylbis[bis(3,5-dimethylphenyl)phosphine] CAS:325168-89-6	C₄₈H₅₀P₂
	\|S\|-(+)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane CAS:325168-88-5	C₄₈H₅₀P₂
	Bisdiphenylphosphinoparacyclophane CAS:192463-40-4	C₄₀H₃₄P₂
	(R)-Phanephos CAS:364732-88-7	C₄₀H₃₄P₂

A catalyst for efficient and highly enantioselective hydrogenation of aromatic, heteroaromatic, and alpha,beta-unsaturated ketones

Abstract

Related Compounds