Organic letters

A novel type of nucleophilic substitution reactions on nonactivated aromatic compounds and benzene itself with trimethylsiliconide anions

A Postigo, RA Rossi

Index: Organic letters, , vol. 3, # 8 p. 1197 - 1200

Full Text: HTML

Citation Number: 18

Abstract

... Volume: Page: ... Organic Letters. ... The reaction of fluorobenzene with Me 3 Si - anion (1) in HMPA at room temperature surprisingly affords o- and p-fluorotrimethylsilylbenzenes (substitution of aromatic H for TMS, 76% yield) 7a and 7b and also 14% of ...