Organic Letters

Unified Total Synthesis of Five Gelsedine-Type Alkaloids:(−)-Gelsenicine,(−)-Gelsedine,(−)-Gelsedilam,(−)-14-Hydroxygelsenicine, and (−)-14, 15- …

T Harada, J Shimokawa, T Fukuyama

Index: Kaise, Hiromi; Shimokawa, Jun; Fukuyama, Tohru Organic Letters, 2014 , vol. 16, # 3 p. 727 - 729

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Abstract

The systematic arrangement of a two-carbon unit, hydrogen atom, and oxygen atom on the versatile enal moiety of a non-natural synthetic intermediate successfully led to the unified access to the gelsedine-type alkaloids. The development and use of this new synthetic hub