Synthesis of Ruthenium Half??Sandwich Complexes by Naphthalene Replacement in [CpRu (C10H8)]+

DS Perekalin, EE Karslyan, EA Trifonova…

Index: Perekalin, Dmitry S.; Karslyan, Eduard E.; Trifonova, Evgeniya A.; Konovalov, Andrew I.; Loskutova, Natalia L.; Nelyubina, Yulia V.; Kudinov, Alexander R. European Journal of Inorganic Chemistry, 2013 , # 4 p. 481 - 493

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Citation Number: 14

Abstract

Abstract Replacement of the naphthalene ligand in ruthenium complex [CpRu (C 10 H 8)]+(1) by halide anions readily proceeds at room temperature to give insoluble oligomeric species [CpRuX] n (X= Cl, Br, I). Similar reactions in the presence of mono-or bidentate ligands afford complexes [CpRuL 2 X] where L= CO, P (OMe) 3, tBuNC; L 2= dppm, dppe, dppp, bipy, phen, cod, nbd, or 1, 4-diphenylbutadiene. Useful catalysts [CpRu (cod) X] ...