Tetrahedron

Novel synthetic approach in microwave-assisted solid-supported oxidations using 'in situ'generated molecular oxygen

E Gershonov, E Katz, Y Karton, Y Zafrani

Index: Gershonov, Eytan; Katz, Esther; Karton, Yishai; Zafrani, Yossi Tetrahedron, 2007 , vol. 63, # 18 p. 3762 - 3767

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Citation Number: 12

Abstract

Three different types of oxidation reactions were carried out under microwave (MW) conditions in dry media, with nearly quantitative yield, using 'in situ', yet separately generated molecular oxygen as the reactive gas. The latter is formed by a controlled decomposition of potassium chlorate (220–306° C) adsorbed on zeolite support, and is used as a reactive oxidizing agent for the solid-supported oxidations. The MW-assisted ...