Acta Crystallographica Section E 2010-01-01

2-[(E)-2-Hy-droxy-5-(trifluoro-meth-oxy)benzyl-idene-amino]-4-methyl-phenol.

Aslı Tosyalı Karadağ, Sehriman Atalay, Hasan Genç

Index: Acta Crystallogr. Sect. E Struct. Rep. Online 67(1) , o95-o95, (2010)

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Abstract

The title compound, C(15)H(12)F(3)NO(3), is a Schiff base which adopts the cis-quinoid form in the solid state. The dihedral angle between the least-squares planes of the benzene rings being 3.6 (1)°. The F atoms of the -CF(3) group are disordered over two sets of sites with refined occupancies of 0.61 (5) and 0.39 (5). An intra-molecular N-H⋯O hydrogen bond occurs. The crystal structure is stabilized by inter-molecular O-H⋯O hydrogen bonds.

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