Acylation through ketene intermediates

R Shelkov, M Nahmany, A Melman

Index: Graham, James M.; Shireman, Brock T.; Maddux, Todd M.; Brandstedt, Christina M.; Zeller, Wayne E. Synthetic Communications, 2000 , vol. 30, # 7 p. 1221 - 1226

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Citation Number: 45

Abstract

... are completed in several minutes even at high dilution (0.01 M) and provide ... for the preparation of nonsymmetric dialkylmalonates that are useful synthons in synthetic organic chemistry. ... the esterification of p-methoxybenzyl malonate (10 mM) in dichloromethane with t-BuOH (10 ...