A Poly (para??phenylene) with Hydrophobic and Hydrophilic Dendrons: Prototype of an Amphiphilic Cylinder with the Potential to Segregate Lengthwise

Z Bo, JP Rabe, AD Schlüter

Index: Bo, Zhishan; Rabe, Juergen P.; Schlueter, A. Dieter Angewandte Chemie - International Edition, 1999 , vol. 38, # 16 p. 2370 - 2372

Full Text: HTML

Citation Number: 155

Abstract

Abstract Langmuir monolayers are formed from an amphiphilically decorated poly (para- phenylene), which indicates that its hydrophilic and hydrophobic parts segregate lengthwise along the polymer backbone in this nanometer-sized cylinder as illustrated in A. This polymer differs from known amphiphiles in that it consists of a linear, covalently bound sequence of “little” amphiphiles. It is much more rigid than common “polysoaps”, which ...