Cruciform π-systems: hybrid phenylene-ethynylene/phenylene-vinylene oligomers

JN Wilson, M Josowicz, Y Wang…

Index: Wilson, James N.; Josowicz, Mira; Wang, Yiqing; Bunz, Uwe H. F. Chemical Communications, 2003 , # 24 p. 2962 - 2963

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Citation Number: 50

Abstract

Is the change in properties indigenous to the polymer backbone, or are single, isolated, cruciforms “cut out” of B responsible for the observed electronic effects? We find that the optical, electronic and redox properties of B reside mostly in their pentameric cruciform 5 modules 3. ... Starting from the bisphosphonate 1 a Horner 6 reaction produced the distyrylbenzenes 2a–e in good to excellent yields (Scheme 1). In the second step 2a–e were coupled to terminal alkynes ...