Displacement Reactions of Neopentyl-type Sulfonate Esters1

JM Sugihara, DL Schmidt, VD Calbi…

Index: Sugihara,J.M. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 1406 - 1409

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Citation Number: 2

Abstract

In the second step, the ease of displacement appears to be: OSO2C6H4Br (p)> OS0&6H6> I> OSOZCSH&H3 (p). Other effects found in these experiments were: dimethyl sulfoxide is less effective than dimethylformamide. A sufficient amount of water is necessary to dissolve jn part the sodium cyanide. Ethanol in a sealed tube is less effective than dimethylformamide as a solvent.