Physical Chemistry Chemical Physics 2007-11-28

Oxygen-17 hyperfine structures in the pure rotational spectra of SrO, SnO, BaO, HfO and ThO.

Christopher T Dewberry, Kerry C Etchison, Garry S Grubbs Ii, Robert A Powoski, Michal M Serafin, Sean A Peebles, Stephen A Cooke

Index: Phys. Chem. Chem. Phys. 9(44) , 5897-901, (2007)

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Abstract

Hyperfine structures arising from the couplings of the nuclear spin angular momentum of (17)O (I = 5/2) with the end over end rotation of several metal-containing diatomic monoxides have been observed using a Fourier transform microwave spectrometer. The molecules have been produced by reacting (17)O(2) with laser ablated metal atoms. The oxygen-17 nuclear quadrupole coupling constants have been determined for the title molecules and are interpreted in terms of a simple Townes-Dailey model. Also, the oxygen-17 nuclear spin-rotation constants have been determined and used to calculate the oxygen-17 shieldings for each molecule.