Acta Crystallographica, Section C: Crystal Structure Communications 2000-10-01

Chloramine-B sesquihydrate.

E George, S Vivekanandan, K Sivakumar

Index: Acta Crystallogr. C 56 ( Pt 10) , 1208-9, (2000)

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Abstract

In the title compound, sodium N-chlorobenzenesulfonamide sesquihydrate, Na(+).C(6)H(5)ClNO(2)S(-).1.5H(2)O, the sodium ion exhibits octahedral coordination by O atoms from three water molecules and by three sulfonyl O atoms of three different N-chlorobenzenesulfonamide anions. A two-dimensional polymeric layer consists of units, each comprising two face-sharing octahedra which share four corners with four other such units, the layer running parallel to the ab plane. The water molecules participate in hydrogen bonds of the types O-H...O, O-H...N and O-H...Cl.