Organoruthenium??Supported Polyoxotungstate–Synthesis, Structure and Oxidation of n??Hexadecane with Air

…, B Wang, HM Sui, B Li, W Song, LX Wu…

Index: Meng, Rui-Qi; Wang, Bin; Sui, Hui-Min; Li, Bao; Song, Wei; Wu, Li-Xin; Zhao, Bing; Bi, Li-Hua European Journal of Inorganic Chemistry, 2013 , # 10-11 p. 1935 - 1942

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Citation Number: 3

Abstract

Abstract A ruthenium complex, KNa [Ru 2 (C 6 H 6) 2 (CH 3 COO) 6](Ru-KNa), and its polyoxotungstate derivative, Na 6 [{Ru (C 6 H 6)} 2 W 8 O 28 (OH) 2]· 16H 2 O (Ru-Na), have been successfully isolated from routine synthetic reactions and characterized by X-ray single- crystal structure analysis, IR spectroscopy and elemental analysis. A remarkable aspect of Ru-KNa is that it has two ligand types, benzene and acetate, and the acetate ligands are ...