A new family of biisoquinoline chelates

…, P Roesel, JP Sauvage, OS Wenger

Index: Durola, Fabien; Hanss, David; Roesel, Pirmin; Sauvage, Jean-Pierre; Wenger, Oliver S. European Journal of Organic Chemistry, 2007 , # 1 p. 125 - 135

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Citation Number: 18

Abstract

Abstract Four 8, 8′-diaryl-substituted 3, 3′-biisoquinoline ligands have been synthesized and characterized. The key feature of this new family of chelates is their endotopic but sterically nonhindering nature. All four ligands were made from a common 8- bromoisoquinolin-3-ol precursor; between three and twelve synthetic steps were necessary to obtain the products. The reported synthetic procedures allow for gram-scale production ...