Palladium Supported on Cross??Linked Imidazolium Network on Silica as Highly Sustainable Catalysts for the Suzuki Reaction under Flow Conditions

…, C Aprile, L Vaccaro, M Gruttadauria

Index: Pavia, Cinzia; Ballerini, Eleonora; Bivona, Lucia Anna; Giacalone, Francesco; Aprile, Carmela; Vaccaro, Luigi; Gruttadauria, Michelangelo Advanced Synthesis and Catalysis, 2013 , vol. 355, # 10 p. 2007 - 2018

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Citation Number: 50

Abstract

Abstract Highly cross-linked imidazolium-based materials, obtained by radical oligomerization of bis-vinylimidazolium salts in the presence of 3-mercaptopropyl-modified silica gel, were used as supports for palladium catalysts. Thanks to the high imidazolium loading these materials were able to support a high amount of the metal (10 wt%). Such materials were characterized by several techniques (13 C magic angle spinning nuclear ...

~10%

~93%

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