Journal of Agricultural and Food Chemistry 2005-05-18

Influence of soil properties on the adsorption-desorption of sulcotrione and its hydrolysis metabolites on various soils.

Hanene Chaabane, Jean-François Cooper, Lamia Azouzi, Camilla-Michel Coste

Index: J. Agric. Food Chem. 53(10) , 4091-5, (2005)

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Abstract

The retention process of sulcotrione and its two hydrolysis products, 1,3-cyclohexanedione (CHD) and 2-chloro-4-methylsulfonylbenzoic acid (CMBA), were studied in four different soils (Belgium, Landes, Perpignan, and Martinique) under laboratory conditions. Adsorption isotherms were well fitted by a Freundlich relationship. The values of K(fa) ranged from 0.4 to 27.0, and the most adsorbed compound was CHD regardless the soil type. Sulcotrione and CMBA exhibited similar retention behaviors. According to adsorption and desorption results, sulcotrione presents a moderate affinity with soil components; however, its leaching capacity needs to be carefully assessed. Clay content seemed to be the most important factor influencing the adsorption capacity of each compound, whereas organic matter and pH had little influence. The soils were classified according to their adsorption capacity in the following decreasing order: Martinique, Belgium, Landes, Perpignan.