Chemical Communications 2005-08-07

Isolation of axial conformers of chloro- and bromocyclohexane in a pure state as inclusion complexes with 9,9'-bianthryl, and the discovery of a novel 1,3 diaxial Cl...H weak interaction.

Shinya Hirano, Shinji Toyota, Masako Kato, Fumio Toda

Index: Chem. Commun. (Camb.) (29) , 3646-8, (2005)

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Abstract

The axial conformers of chloro- and bromocyclohexane were isolated in a pure state as inclusion complexes with 9,9'-bianthryl, and a 1,3 diaxial Cl...H weak interaction was discovered by X-ray analysis of the axial conformer of chlorocyclohexane.