Journal - Association of Official Analytical Chemists 1986-01-01

On-line trace enrichment for determination of aldicarb species in water, using liquid chromatography with post-column derivatization.

D Chaput

Index: J. Assoc. Off. Anal. Chem. 69(6) , 985-9, (1986)

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Abstract

Liquid chromatography combining on-line trace enrichment together with a very selective detection technique is used for the determination of aldicarb, aldicarb sulfoxide, and aldicarb sulfone. Sensitivity is increased by loading a 10 mL volume of ground water on a concentrator column installed in the loop position of a 6-port injection valve. Switching the valves allows the concentrated material to be backflushed onto the analytical column by a methanol-water gradient mobile phase. Separation is followed by post-column hydrolysis to yield methylamine, and formation of a fluorophore with o-phthalaldehyde and 2-mercaptoethanol prior to fluorescence detection. The process requires virtually no sample cleanup and provides good precision on recoveries from different matrixes. Minimum detection limit, defined as 5 times baseline noise, is less than 70 ng/L for the 3 compounds.