Synthesis and Solid-State Polymerization of Butadiyne Derivatives with Trialkoxyphenylurethane Groups

…, Y Tatewaki, S Okada, T Kimura, S Shimada…

Index: Takahashi, Rintaro; Nunokawa, Tatsuya; Shibuya, Tadahiro; Tomita, Ryohei; Tatewaki, Yoko; Okada, Shuji; Kimura, Tatsumi; Shimada, Satoru; Matsuda, Hiro Bulletin of the Chemical Society of Japan, 2012 , vol. 85, # 2 p. 236 - 244

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Citation Number: 5

Abstract

3, 4, 5-Trialkoxyphenyl isocyanate derivatives, in which alkoxy was dodecyloxy or methoxy, reacted with 4, 6-decadiyn-1, 10-diol and 5, 7-dodecadiyn-1, 12-diol, and four butadiyne derivatives with (N-trialkoxyphenyl) urethane groups were successfully synthesized. Their solid-state polymerization stimulated by UV or γ-ray irradiation was investigated. All monomers in crystals were found to be polymerizable. However, conversion was different ...