Tetrahedron Letters

Cyanuric chloride: an efficient reagent for the Lossen rearrangement

F Hamon, G Prié, F Lecornué, S Papot

Index: Hamon, Florian; Prie, Gildas; Lecornue, Frederic; Papot, Sebastien Tetrahedron Letters, 2009 , vol. 50, # 49 p. 6800 - 6802

Full Text: HTML

Citation Number: 32

Abstract

An efficient method for the Lossen rearrangement that uses 2, 4, 6-trichloro-1, 3, 5-triazine (TCT) as a promoter is reported. This procedure allowed the preparation of various carbamates, thiocarbamates, and ureas in good yields directly from the corresponding hydroxamic acids.

~87%

~88%

~81%

~99%

~80%

~71%

~65%

A novel catalytic synthesis of carbamates by oxydative alkox...

[Fukuoka, Shinsuke; Chono, Masazumi; Kohno, Masashi Journal of the Chemical Society, Chemical Communications, 1984 , # 6 p. 399 - 400]

Reaction of organozinc halides with aryl isocyanates

[Yang, Haoran; Huang, Danfeng; Wang, Ke-Hu; Xu, Changming; Niu, Teng; Hu, Yulai Tetrahedron, 2013 , vol. 69, # 12 p. 2588 - 2593]

The reaction of amines with an electrogenerated base. Improv...

[Feroci, Marta; Inesi, Achille; Rossi, Leucio Tetrahedron Letters, 2000 , vol. 41, # 6 p. 963 - 966]

A novel PdCl 2/ZrO 2–SO 2− 4 catalyst for synthesis of carba...

[Journal of Catalysis, , vol. 203, # 2 p. 525 - 528]

Mild and selective deprotection of carbamates with Bu 4 NF

[Jacquemard, Ulrich; Beneteau, Valerie; Lefoix, Myriam; Routier, Sylvain; Merour, Jean-Yves; Coudert, Gerard Tetrahedron, 2004 , vol. 60, # 44 p. 10039 - 10047]