Lithium Alkylamide-Catalyzed Addition Reaction of Alkylamines to Vinyl Monomers. III. Addition Reaction of p-Substituted Benzylamines to Styrene and …

H Hamana, F Iwasaki, H Nagashima, K Hattori…

Index: Hamana, Hiroshi; Iwasaki, Fuminori; Nagashima, Hiroyoshi; Hattori, Kazuhisa; Hagiwara, Tokio; Narita, Tadashi Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 4 p. 1109 - 1113

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Citation Number: 5

Abstract

The lithium alkylamide-catalyzed addition reaction of p-substituted benzylamines with m-and p-divinylbenzene was examined in order to synthesize new styrene derivatives. Though divinylbenzene possesses two vinyl groups, 1: 1 adducts, the N-(p-substituted benzyl) vinylphenethylamines (6, 8) were found to be prepared selectively. The reaction with styrene was also examined as a model reaction. From kinetic studies, the Hammett p values for ...